Krein's Theorem is a fundamental result in spectral theory that addresses the essential self-adjointness of certain unbounded operators, particularly in the context of differential operators on a Hilbert space. It provides necessary and sufficient conditions under which an operator, which may not be self-adjoint on its domain, can be extended to a self-adjoint operator. This theorem is crucial in understanding the spectral properties of operators, as essential self-adjointness ensures that the operator's spectrum behaves well and guarantees the uniqueness of the self-adjoint extension.
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