Sugar Alcohols

Definition

Sugar alcohols, also known as polyols, are a class of carbohydrates that resemble the chemical structure of both sugars and alcohols. They are commonly used as sweeteners and found in various food and pharmaceutical products.

5 Must Know Facts For Your Next Test

1. Sugar alcohols are not fully absorbed by the body, resulting in a lower caloric content compared to regular sugars.
2. They are often used as low-calorie sweeteners in sugar-free and diabetic-friendly products, as they have a lower glycemic index.
3. Sugar alcohols can have a laxative effect in large quantities, as they are not completely broken down and absorbed in the small intestine.
4. Some sugar alcohols, like xylitol, have been shown to have dental health benefits by inhibiting the growth of harmful bacteria in the mouth.
5. The production of sugar alcohols involves the hydrogenation of sugars, where the carbonyl group is reduced to a hydroxyl group.

Review Questions

• Explain how the chemical structure of sugar alcohols differs from regular sugars and how this affects their properties.
  • Sugar alcohols have a similar chemical structure to sugars, but with the carbonyl group reduced to a hydroxyl group. This structural difference results in sugar alcohols being less readily absorbed by the body, leading to a lower caloric content compared to regular sugars. Additionally, the presence of multiple hydroxyl groups contributes to the sweetness and reduced glycemic impact of sugar alcohols, making them a popular choice as low-calorie sweeteners in various food and pharmaceutical applications.
• Describe the potential health benefits and drawbacks associated with the use of sugar alcohols.
  • Sugar alcohols can provide several health benefits, such as lower caloric content, reduced impact on blood sugar levels, and potential dental health advantages (e.g., inhibiting the growth of harmful oral bacteria). However, they can also have drawbacks, including a laxative effect when consumed in large quantities, as they are not completely broken down and absorbed in the small intestine. This can lead to gastrointestinal discomfort and other digestive issues. Therefore, the use of sugar alcohols requires moderation and consideration of individual tolerance and sensitivity.
• Analyze the role of sugar alcohols in the context of the reactions of monosaccharides, and discuss how their unique properties might influence these reactions.
  • In the context of the reactions of monosaccharides, the presence of sugar alcohols can introduce additional considerations. The reduced carbonyl group and increased hydroxyl groups in sugar alcohols may alter the reactivity and behavior of these compounds compared to regular sugars. For example, the hydrogenation process used to produce sugar alcohols can affect the stereochemistry and reactivity of the monosaccharide units, potentially influencing their ability to undergo certain reactions, such as oxidation, reduction, or condensation reactions. Additionally, the lower absorption and metabolic processing of sugar alcohols may impact their involvement in various metabolic pathways and reactions involving monosaccharides. Understanding these nuances is crucial when studying the reactions of monosaccharides in the presence of sugar alcohols.

Related terms

Polyols: An alternative name for sugar alcohols, referring to their chemical structure containing multiple alcohol groups.

Sorbitol: A sugar alcohol commonly used as a sweetener and found in fruits like apples, pears, and plums.

Xylitol: A sugar alcohol with a sweet taste that is commonly used as a sugar substitute, particularly in chewing gum and dental products.