Addition polymerization

Definition

Addition polymerization is a chemical reaction in which monomers containing double bonds or other reactive groups combine to form a polymer without the loss of any small molecules. This process is characterized by the sequential addition of monomer units, leading to the growth of long-chain molecules, and it is crucial for understanding the mechanisms and kinetics involved in step-growth polymerization.

5 Must Know Facts For Your Next Test

1. Addition polymerization typically involves monomers that have carbon-carbon double bonds, such as alkenes, which react under specific conditions to form polymers.
2. This type of polymerization can occur via various mechanisms, including free radical, cationic, and anionic pathways, each having unique initiators and conditions.
3. The reaction proceeds through initiation, propagation, and termination stages, where the growth of the polymer chain is dictated by the concentration of reactants and conditions.
4. Addition polymerization leads to polymers with high molecular weights and can create materials like polyethylene and polystyrene, commonly used in various applications.
5. Unlike step-growth polymerization, addition polymerization does not require the formation of small byproducts, making it a cleaner reaction in terms of side products.

Review Questions

• How does the mechanism of addition polymerization differ from that of step-growth polymerization?
  • Addition polymerization differs from step-growth polymerization primarily in its mechanism where the reaction occurs via chain growth rather than stepwise reactions. In addition polymerization, monomers with unsaturated bonds undergo a continuous addition process through initiation, propagation, and termination stages. In contrast, step-growth polymerization involves the gradual reaction between functional groups leading to larger structures without necessarily having an active center throughout the process.
• Discuss how temperature and pressure affect the kinetics of addition polymerization compared to step-growth polymerization.
  • Temperature and pressure significantly influence the kinetics of addition polymerization because they affect the reactivity of monomers and the stability of intermediates like free radicals. Higher temperatures typically increase the rate of initiation and propagation by providing more energy for molecular collisions, while pressure can enhance the concentration of gaseous monomers. In comparison, step-growth polymerization is often less sensitive to these conditions as it relies more on the concentration of functional groups rather than on chain initiation events.
• Evaluate the environmental implications of addition polymerization in industrial applications compared to traditional methods of producing polymers.
  • The environmental implications of addition polymerization are significant when evaluating industrial applications, particularly concerning waste generation and resource usage. Since addition polymerization does not produce small byproducts, it can be viewed as a cleaner method compared to traditional methods that may generate excess materials. However, the reliance on petroleum-based feedstocks for many monomers poses sustainability concerns. As a result, exploring bio-based alternatives for monomers in addition polymerization processes can contribute positively to reducing environmental impact and promoting sustainability in material production.

Related terms

Monomer: A small molecule that can join together with other monomers to form a polymer through chemical reactions.

Chain reaction: A sequence of reactions where the product of one reaction initiates another reaction, commonly seen in addition polymerization processes.

Free radical: An atom or molecule that has unpaired electrons and can initiate chain reactions in addition polymerization by reacting with monomers.