Primitive Pythagorean triples are sets of three positive integers $(a, b, c)$ that satisfy the equation $$a^2 + b^2 = c^2$$ and have no common divisor greater than 1. This means that each integer in the triple is relatively prime to the others. These triples are significant because they represent the simplest forms of Pythagorean triples, which form the basis for understanding relationships between sides of right triangles and contribute to the study of irrational numbers through their geometric interpretations.
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