Bond angle

Definition

A bond angle is the geometric angle formed between two adjacent bonds in a molecule, measured at the central atom. It is a crucial factor in determining the shape and spatial arrangement of molecules, influencing their physical and chemical properties. Understanding bond angles helps in predicting molecular geometry and reactivity, which are fundamental concepts in the study of ionic and covalent bonding.

5 Must Know Facts For Your Next Test

1. Bond angles are influenced by the number of lone pairs and bonding pairs around the central atom, as described by VSEPR theory.
2. Different molecular shapes, such as linear, trigonal planar, and tetrahedral, correspond to specific bond angles like 180°, 120°, and 109.5° respectively.
3. In covalent compounds, bond angles can deviate from ideal angles due to steric effects and the presence of lone pairs.
4. Ionic compounds generally do not have defined bond angles like covalent compounds because they consist of a lattice structure instead of discrete molecules.
5. Accurate predictions of bond angles can help chemists understand the reactivity and interaction patterns of different molecules.

Review Questions

• How does VSEPR theory explain the relationship between bond angles and molecular geometry?
  • VSEPR theory explains that bond angles are determined by the repulsion between electron pairs surrounding a central atom. The theory posits that electron pairs will arrange themselves to minimize repulsion, leading to specific geometric shapes for different types of molecules. For example, in a tetrahedral arrangement, the four bonding pairs spread out to form bond angles of approximately 109.5°, while in a trigonal planar arrangement, three bonding pairs create bond angles of about 120°.
• Compare the bond angles in a water molecule (H₂O) versus carbon dioxide (CO₂) and explain the factors that influence their differences.
  • In a water molecule (H₂O), the bond angle is approximately 104.5° due to the presence of two lone pairs on oxygen, which push the hydrogen atoms closer together. In contrast, carbon dioxide (CO₂) has a linear structure with a bond angle of 180° because there are no lone pairs on the central carbon atom; both oxygen atoms are bonded directly opposite each other. The lone pairs in H₂O cause greater repulsion than bonding pairs alone, resulting in a smaller bond angle.
• Evaluate how understanding bond angles can influence predictions about a molecule's reactivity and interactions with other substances.
  • Understanding bond angles is essential for predicting how molecules will interact with one another during chemical reactions. For example, if a molecule has significant deviations from ideal bond angles due to steric hindrance or lone pair repulsion, it may exhibit unexpected reactivity or steric effects that influence how it approaches other molecules. This knowledge allows chemists to tailor reactions or design new compounds by considering how molecular geometry affects reactivity patterns and compatibility with other chemical species.

Related terms

molecular geometry: The three-dimensional arrangement of atoms in a molecule that influences its shape and bond angles.

VSEPR theory: A model used to predict the geometry of molecules based on the repulsion between electron pairs surrounding a central atom.

hybridization: The concept of mixing atomic orbitals to form new hybrid orbitals, which helps explain bond angles and molecular geometry.