Advanced Chemical Engineering Science

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Stokes' Law

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Advanced Chemical Engineering Science

Definition

Stokes' Law describes the motion of spherical particles through a viscous fluid, stating that the force resisting the motion of the particle is proportional to its radius and the velocity at which it moves. This law is fundamental in understanding how solids behave when immersed in fluids, providing insights into sedimentation, filtration, and various industrial processes involving solid-fluid systems.

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5 Must Know Facts For Your Next Test

  1. Stokes' Law is expressed mathematically as F = 6πμrv, where F is the drag force, μ is the fluid's viscosity, r is the particle radius, and v is the particle's velocity.
  2. The law applies primarily to small particles moving slowly through a viscous medium, typically when Reynolds numbers are less than 0.1.
  3. In practical applications, Stokes' Law is critical for designing equipment in industries like chemical engineering, pharmaceuticals, and water treatment.
  4. Understanding Stokes' Law helps in predicting the settling rate of particles in sedimentation tanks, aiding in the design of effective separation processes.
  5. Factors such as particle shape and size significantly influence how accurately Stokes' Law can predict motion; non-spherical particles may require modifications to the basic equation.

Review Questions

  • How does Stokes' Law relate to the behavior of particles in a viscous fluid, and what factors influence its applicability?
    • Stokes' Law outlines how spherical particles move through viscous fluids, emphasizing that factors like particle size, fluid viscosity, and velocity significantly affect motion. The law works best for small particles at low velocities in fluids with low turbulence. If conditions deviate from these parameters or if particles are non-spherical, modifications to the basic law may be necessary for accurate predictions.
  • Discuss how Stokes' Law can be applied in industrial processes for solid-fluid separation.
    • In industrial processes such as sedimentation and filtration, Stokes' Law provides a framework for predicting how quickly solid particles will settle in a liquid. By understanding the drag force acting on these particles based on their size and the viscosity of the fluid, engineers can design more efficient separation equipment. This application is crucial for optimizing processes in industries like wastewater treatment and pharmaceuticals.
  • Evaluate the limitations of Stokes' Law when applied to real-world scenarios involving non-spherical or larger particles.
    • While Stokes' Law offers valuable insights into particle motion in fluids, its limitations become apparent with non-spherical or larger particles. As particle shape diverges from spherical or size increases significantly, assumptions made in Stokes' Law regarding drag force may no longer hold true. In such cases, corrections must be made using empirical data or more complex fluid dynamics models to accurately describe behavior, highlighting the need for careful analysis in practical applications.
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